Delocalization and stretch-bend mixing of the HOH bend in liquid water.

Abstract

Liquid water's rich sub-picosecond vibrational dynamics arise from the interplay of different high- and low-frequency modes evolving in a strong yet fluctuating hydrogen bond network. Recent studies of the OH stretching excitations of H2O indicate that they are delocalized over several molecules, raising questions about whether the bending vibrations are… (More)
DOI: 10.1063/1.4987153

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Cite this paper

@article{Carpenter2017DelocalizationAS, title={Delocalization and stretch-bend mixing of the HOH bend in liquid water.}, author={William B Carpenter and Joseph A Fournier and Rajib Biswas and Gregory A Voth and Andrei Tokmakoff}, journal={The Journal of chemical physics}, year={2017}, volume={147 8}, pages={084503} }