Definition of the hydrogen bond (IUPAC Recommendations 2011)
@article{Arunan2011DefinitionOT, title={Definition of the hydrogen bond (IUPAC Recommendations 2011)}, author={Elangannan Arunan and Gautam R. Desiraju and Roger A. Klein and Joanna Sadlej and Steve Scheiner and Ibon Alkorta and David C. Clary and Robert H. Crabtree and J. J. Dannenberg and Pavel Hobza and Henrik G. Kjaergaard and Anthony C. Legon and Benedetta Mennucci and David J. Nesbitt}, journal={Pure and Applied Chemistry}, year={2011}, volume={83}, pages={1637 - 1641} }
A novel definition for the hydrogen bond is recommended here. It takes into account the theoretical and experimental knowledge acquired over the past century. This definition insists on some evidence. Six criteria are listed that could be used as evidence for the presence of a hydrogen bond.
1,045 Citations
Definition of the chalcogen bond (IUPAC Recommendations 2019)
- ChemistryPure and Applied Chemistry
- 2019
Abstract This recommendation proposes a definition for the term “chalcogen bond”; it is recommended the term is used to designate the specific subset of inter- and intramolecular interactions formed…
Special Issue: Intramolecular Hydrogen Bonding 2017
- ChemistryMolecules
- 2017
Even after more than a century of study [1-6], scrutiny, and detailed examination, the H-bond continues [7-12] to evoke a level of fascination that surpasses many other phenomena [...].
Intermolecular atom–atom bonds in crystals – a chemical perspective1
- ChemistryIUCrJ
- 2015
Short atom–atom distances between molecules are almost always indicative of specific intermolecular bonding. These distances may be used to assess the significance of all hydrogen bonds, including…
Why are Hydrogen Bonds Directional?
- ChemistryJournal of Chemical Sciences
- 2016
AbstractThe recent IUPAC recommendation on the definition of hydrogen bonding points out that directionality is a defining characteristic of a hydrogen bond and the angle ∠X-H-Y is generally linear…
Catalysis and Molecular Recognition: Harnessing Hydrogen Bonds and the Power of Charged Substituents
- Chemistry
- 2015
University of Minnesota Ph.D. dissertation. July 2015. Major: Chemistry. Advisor: Steven Kass. 1 computer file (PDF); xiv, 174 pages.
Coordination chemistry of anions through halogen-bonding interactions.
- Chemistry, Materials ScienceActa crystallographica Section B, Structural science, crystal engineering and materials
- 2017
This special issue devoted to halogen bonding illustrates recent developments associated with this interaction in crystal engineering, unravelling here unusual trends of a coordination chemistry of halide anions.
What is a hydrogen bond? Resonance covalency in the supramolecular domain
- Chemistry
- 2014
Both direct and statistical lines of evidence point to the essential resonance covalency of H-bonding interactions, rather than the statistically insignificant “dipole–dipoles” character that is persistently advocated in current textbooks.
Cellulose and the role of hydrogen bonds: not in charge of everything
- Materials ScienceCellulose
- 2021
In the cellulose scientific community, hydrogen bonding is often used as the explanation for a large variety of phenomena and properties related to cellulose and cellulose based materials. Yet,…
Naming Interactions from the Electrophilic Site
- Chemistry
- 2014
It is proposed that noncovalent interactions, wherein it is possible to identify an element or moiety working as the electrophile, are named by referring to the Group of the Periodic Table the…
References
SHOWING 1-10 OF 17 REFERENCES
The Weak Hydrogen Bond: In Structural Chemistry and Biology
- Chemistry, Materials Science
- 1999
The weak hydrogen bond in supramolecular chemistry and its role in biological structures is described and other weak and non-conventional hydrogen bonds are described.
An Introduction to Hydrogen Bonding
- Chemistry, Materials Science
- 1997
1. Brief History 2. Nature and Properties 3. Strong Hydrogen Bonds 4. Moderate Hydrogen Bonds 5. Weak Hydrogen Bonds 6. Cooperativity, Patterns, Graph Set Theory, Liquid Crystals 7. Disorder, Proton…
Hydrogen Bonding: A Theoretical Perspective
- Physics, Chemistry
- 1997
1. Quantum Chemical Framework 2. Geometries and Energetics 3. Vibrational Spectra 4. Extended Regions of Potential Energy Surface 5. Cooperative Phenomena 6. Questionable Cases
Hydrogen Bonding—New Insights
- Chemistry, Materials Science
- 2006
I. Characterization of Hydrogen Bonding: From van der Waals Interactions to Covalency, R. Parthasarathi and V. Subramanian II. Intramolecular Hydrogen Bonds. Methodologies and Strategies for their…
Hydrogen Bonding in Biological Structures
- Chemistry, Materials ScienceSpringer Berlin Heidelberg
- 1991
IA Basic Concepts.- 1 The Importance of Hydrogen Bonds.- 1.1 Historical Perspective.- 1.2 The Importance of Hydrogen Bonds in Biological Structure and Function.- 1.3 The Role of the Water Molecules.-…
Atoms in molecules : a quantum theory
- Chemistry, Physics
- 1990
List of symbols 1. Atoms in chemistry 2. Atoms and the topology of the charge desnity 3. Molecular structure and its change 4. Mathematical models of structural change 5. The quantum atom 6. The…
X-ray charge densities and chemical bonding
- Physics
- 1997
1. Scattering of X-rays and Neutrons 2. The Effect of Thermal Vibrations on the Intensities of the Diffracted Beams 3. Chemical Bonding and the X-ray Scattering Formalism 4. Least-squares Methods and…
Atomic and Molecular Beam Methods
- Physics
- 1988
Part I: Spectroscopy. 1: Spectroscopy of molecular beams: an overview. 2: Magnetic and electric resonance spectroscopy. 3: Beam-maser spectroscopy. 4: Quantum amplifiers and oscillators. 5: Metrology…
IUPAC Pure Appl. Chem
- IUPAC Pure Appl. Chem
- 2011