Defective Metal-Organic Frameworks Incorporating Iridium-Based Metalloligands: Sorption and Dye Degradation Properties.

Abstract

Artificial control and engineering of metal-organic framework (MOF) crystals with defects can endow them with suitable properties for applications in gas storage, separation, and catalysis. A series of defective iridium-containing MOFs, [Zn4 (μ4 -O)(Ir-A)2(1-x) (Ir-B)2x ] (ZnIr-MOF-dx ), were synthesized by doping heterostructured linker Ir-BH3 into the… (More)
DOI: 10.1002/chem.201700365

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