Decoding the Three-Pronged Mechanism of NO3• Radical Formation in HNO3 Solutions at 22 and 80 °C Using Picosecond Pulse Radiolysis.

Abstract

With nitric acid (HNO3) being at the core of nuclear technology through actinides separation and extraction processes, achieving a complete characterization of the complex processes involving concentrated HNO3 solutions under ionizing radiation equates bringing efficiency and safety into their operation. In this work, the three mechanisms contributing to… (More)
DOI: 10.1021/acs.jpcb.7b12702

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