Deciphering the Spatial Arrangement of Metals and Correla-tion to Reactivity in Multivariate Metal-Organic Frameworks.

Abstract

Thirty-six porphyrin based metal-organic frameworks (MOFs) with composition of (M3O)2(TCPP-M)3 and M3O trigonal SBUs of various metals, Mg3O, Mn3O, Co3O, Ni3O, and Fe3O including mixed-metal SBUs, MnxFe3-xO, NixFe3-xO, CoxNi3-xO, MnxCo3-xO, MnxMg3-xO, and MnxNi3-xO were synthesized and characterized. These multivariate MOFs (MTV-MOFs) were examined by X-ray… (More)

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Cite this paper

@article{Liu2016DecipheringTS, title={Deciphering the Spatial Arrangement of Metals and Correla-tion to Reactivity in Multivariate Metal-Organic Frameworks.}, author={Qi Liu and Hengjiang Cong and Hexiang Deng}, journal={Journal of the American Chemical Society}, year={2016} }