Darstellung, Reaktionen und 51V-NMR-spektroskopische Untersuchungen der Imidovanadium(V)-trichloride: RN=VC13 (R = H, SiMe3, Alkyl) Synthesis, Reactions and 51V NMR Spectroscopic Studies of Imidovanadium(V) Trichlorides: RN=VC13 (R = H, SiMe3, Alkyl)

@inproceedings{Preu2013DarstellungRU,
  title={Darstellung, Reaktionen und 51V-NMR-spektroskopische Untersuchungen der Imidovanadium(V)-trichloride: RN=VC13 (R = H, SiMe3, Alkyl) Synthesis, Reactions and 51V NMR Spectroscopic Studies of Imidovanadium(V) Trichlorides: RN=VC13 (R = H, SiMe3, Alkyl)},
  author={Fritz Preu\ss and Uwe Fischbeck and Frank Tabellion and Jens Pemer},
  year={2013}
}
Z. Naturforsch. 56 b, 255-262 (2001); eingegangen am 23. November 2000 Imidovanadium(V) Trichlorides The reactions of Me3SiN=VCl3 (1) with MeOH, PhOH, HCl, PyH+Cl~ or LiO'Bu have been studied. The reductive decomposition of 1 by hydrogen chloride in toluene yields HN=VC13 as a labile intermediate which could be isolated only in a small amount. The syntheses… CONTINUE READING