DEMYSTIFYING AND UNRAVELLING THE MOLECULAR STRUCTURE OF THE BIOPOLYMER SPOROPOLLENIN.

@article{Mikhael2020DEMYSTIFYINGAU,
  title={DEMYSTIFYING AND UNRAVELLING THE MOLECULAR STRUCTURE OF THE BIOPOLYMER SPOROPOLLENIN.},
  author={Abanoub Mikhael and Kristina Jur{\vc}i{\'c} and C{\'e}line M. Schneider and David Karr and Gregory L. Fisher and Travis D Fridgen and Alberto Diego-Taboada and Paris E. Georghiou and Grahame Mackenzie and Joseph H Banoub},
  journal={Rapid communications in mass spectrometry : RCM},
  year={2020}
}
RATIONALE We report the unsolved molecular structure of the complex biopolymer sporopollenin exine extracted form Lycopodium clavatum pollen grains. METHODS TOF-SIMS and CID-MS/MS, MALDI-TOF-MS and CID-TOF/TOF-MS/MS were used for the analysis of this complex biopolymer sporopollenin exine extracted from Lycopodium clavatum. Solid-state 1 H- and 13 C-NMR, 2D 1 H-1 H NOESY, Rotor-synchronized 13 C{1 H} HSQC, and 13 C{1 H} multi CP-MAS NMR experiments were used to confirm the structural… 

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