20 Citations
Homoconjugation in Light-Emitting Poly(phenylene methylene)s: Origin and Pressure-Enhanced Photoluminescence
- Chemistry
- 2020
The surprising optical properties of the non-π-conjugated polymer poly(phenylene methylene) (PPM) and its derivatives—that is, absorption in the 350–450 nm and photoluminescence (PL) in the 400–600...
Putative Biomimetic Route to 8-Oxabicyclo[3.2.1]octane Motif from a Humulene Sesquiterpenoid Zerumbone.
- ChemistryOrganic letters
- 2020
The present work sheds light on the possible role of UV irradiation in the biosynthesis of oxo-bridged tricyclic structures from polyene terpenes.
High-efficiency blue thermally activated delayed fluorescence from donor–acceptor–donor systems via the through-space conjugation effect
- ChemistryChemical science
- 2019
Highly efficient sky-blue TADF donor–acceptor–donor molecules were demonstrated, in which 5,10-diphenyl-5,10-dihydrophosphanthrene oxide (DPDPO2A) with the feature of homoconjugation was used as the…
Synthesis and fractionation of poly(phenylene methylene)
- Chemistry, Materials Science
- 2018
Poly(phenylene methylene) (PPM) was isolated in a broad range of molar masses by optimization of the catalytic polymerization of benzyl chloride with SnCl4 or FeCl3, followed by fractionation by…
Homoconjugation in poly(phenylene methylene)s: A case study of non‐π‐conjugated polymers with unexpected fluorescent properties
- Materials Science, Chemistry
- 2017
Poly(phenylene methylene) (PPM) exhibits pronounced blue fluorescence in solutions as well as in the solid state despite its non-π-conjugated nature. Optical spectroscopy was used to explore the…
The Thia‐Michael Reactivity of Zerumbone and Related Cross‐Conjugated Dienones: Disentangling Stoichiometry, Regiochemistry, and Addition Mode with an NMR‐Spectroscopy‐Based Cysteamine Assay
- Chemistry, Biology
- 2015
A substantial separation between Michael reactivity and biological activity was found for 1a and its analogues, which supports the view that shape complementarity plays a critical role in the covalent binding of Michael acceptors to their macromolecular target(s).
Cyclopropyl Homoconjugation—Experimental Facts and Interpretations
- Chemistry
- 2009
1
Introduction
2
Homoconjugation in Acyclic Systems
3
Monohomoaromatic and Homoantiaromatic Cations
4
Higher Homoaromatic Cations
5
Neutral Homoaromatic Systems
6
Homoaromatic…
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