Cyclic dimers of tetrafluorobutatriene

  title={Cyclic dimers of tetrafluorobutatriene},
  author={C. Ehm and D. Lentz},
  journal={Theoretical Chemistry Accounts},
Abstract1,1,4,4-Tetrafluorobutatriene polymerizes even at −78 °C within a short time yielding a red insoluble polymer. Possible closed-shell cyclic dimers and oligomers resulting from several reaction paths were analyzed by computational methods—with CCSDT/cc-pVTZ as the highest order calculation and several other calculations of lower level. For a better understanding of fluorination effects, the perhydrogen triene dimers were included in this study. The destabilization of the central… Expand
Synthesis of Organo-fluorine Compounds by Metal Complex-mediated and -Catalyzed Transformations of Fluoro-alkenes and Fluoro-arenes
.......................................................................................................................................... ii AcknowledgementsExpand


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