Crystal structure of lead acetate trihydrate

  title={Crystal structure of lead acetate trihydrate},
  author={Rajamohan Rajaram and J. K. Mohana Rao},
  journal={Zeitschrift f{\"u}r Kristallographie - Crystalline Materials},
  pages={225 - 234}
  • R. Rajaram, J. Rao
  • Published 1982
  • Chemistry
  • Zeitschrift für Kristallographie - Crystalline Materials
Lead acetate trihydrate crystallizes in a tetramolecular, monoclinic unit cell of dimensions a = 15.85(1), b = 7.30(1), c = 9.10(1)A, β = 109.8(5)° in the space group C2/m. The crystal structure has been solved by the heavy-atom method and refined to an R value of 0.096 for 790 observed reflections. Nine oxygen atoms belonging to the water molecules and acetate groups coordinate the lead atom whose coordination polyhedron is a monocapped square antiprism. The two crystallographically different… 

Figures and Tables from this paper


The crystal and molecular structure of lead hexa‐antipyrine perchlorate
Lead hexa-antipyrine perchlorate is isomorphous with a series of metal hexa-antipyrine perchlorates, M(C 11 H 12 ON 2 ) 6 (CIO 4 ) 2 , where M = Mg 2+ , Ca 2+ or Zn 2+ and crystallizes in a hexagonal
Reexamination of the crystal structure of phosgenite, Pb2Cl2(CO3)
Phosgenite, Pb2Cl2(CO3), crystallizes tetragonal witha=8.160(4) A,c=8.883(6) A; space groupP 4/m bm,Z=4. The refinement of 320 crystallographically independent reflections measured on an automatic
The crystal structure of calcium 5-keto-d-gluconate (calcium d-xylo-5-hexulosonate)
The structure, determined by three-dimensional Fourier methods, exhibits a lactol arrangement of the 5-keto-D-gluconate ion, with eightfold coordination of the calcium atom (CaO, 2.46 A; C a H20,
EPR studies of radiation damage in metal acetates: The hydrated lead (II) salt
An EPR study of x‐irradiated lead acetate trihydrate at 77 °K has strengthened the identification of two recently reported species, Pb1+ and PbH2+. The first of these results from radiation‐induced
It is proposed that the arrangements of the electron pairs in the valency shell of a central atom of a polyatomic molecule can be predicted by considering the equilibrium arrangements of similar
Relativistic Calculation of Anomalous Scattering Factors for X Rays
Anomalous scattering factors Δf′ and Δf″ have been calculated relativistically for Cr, Fe, Cu, Mo, and Ag Kα radiations for the atoms Li through Cf. An interpolation scheme for other wavelengths is
On the geometry of Ο — Η . . . O hydrogen bond
  • Acta Crystallogr . A
  • 1976
Reexamination of the crystal structure of phosgenite Pb 2 Cl 2 ( C 0 3 )
  • Tschermaks Mineral . Petrogr . Mitt .
  • 1974