Crystal structure of dimethyl-1κ2 C-bis(μ-4-methylphenolato-1:2κ2 O:O)(N,N,N′,N′-tetramethylethylenediamine-2κ2 N,N′)indium(III)lithium(I)


The mixed bimetallic title compound, [InLi(CH3)2(C7H7O)2(C6H16N2)] or [(tmeda)Li-μ-(4-MeC6H4O)2InMe2] (tmeda is N,N,N',N'-tetra-methyl-ethylenedi-amine), exhibits a four-membered LiO2In ring core via bridging 4-methyl-phenolate groups. The Li and In atoms are in distorted tetra-hedral N2O2 and C2O2 bonding environments, respectively. The Li atom is further… (More)
DOI: 10.1107/S2056989015023476

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