Crystal structure of dichloro-(3-cyclopentadienyl-3-methyl-1-phenylbutyliden- 2,6-dimethylphenylamino)chromium(III), CrCl2(C24H26N)

@article{Steiner2006CrystalSO,
  title={Crystal structure of dichloro-(3-cyclopentadienyl-3-methyl-1-phenylbutyliden- 2,6-dimethylphenylamino)chromium(III), CrCl2(C24H26N)},
  author={Gesine Steiner and Klaus Wurst and Benno Bildstein and Holger Kopacka},
  journal={Zeitschrift f{\"u}r Kristallographie - New Crystal Structures},
  year={2006},
  volume={221},
  pages={303 - 304}
}
C24H26Cl2CrN, monoclinic, P121/c1 (no. 14), a = 11.5168(5) Å, b = 13.9721(6) Å, c = 14.1146(4) Å, = 104.628(2)°, V = 2197.6 Å, Z = 4, Rgt(F) = 0.039, wRref(F) = 0.095, T = 233 K. Source of material The chromium complex was obtained by methods analogous to Huang’s [1] procedure: First, the ketimine of acetophenone and 2,6-dimethylaniline were formed. Second, deprotonation with lithium diisopropylamide afforded the corresponding -lithiated ketimine. Third, nucleophilic addition of this anion to… CONTINUE READING

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