Crystal Structure of Solid Hydrogen Chloride and Deuterium Chloride

@article{Sndor1967CrystalSO,
  title={Crystal Structure of Solid Hydrogen Chloride and Deuterium Chloride},
  author={E. S{\'a}ndor and Reginald C Farrow},
  journal={Nature},
  year={1967},
  volume={213},
  pages={171-172}
}
IT has long been known from measurements of specific heat1 that solid hydrogen chloride undergoes a first order phase transition at about 98.4° K. A similar phase transition was later found2 in solid deuterium chloride at about 105.0° K. X-ray powder photographs3 revealed that the crystal structure of hydrogen chloride was orthorhombic below the transition point and cubic above it. They also indicated that the chlorine atoms formed a face-centred lattice in both phases, but gave no clue… 
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The current work discovered the disorder-order structural transition in HCl and extended its phase diagram to the high pressure-temperature range, also providing a new insight into other simple hydrogen-bonded molecular compounds.
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Although the nuclear magnetic resonance condition generally depends only on the gyromagnetic ratio of the resonanting nuclei, the width and amplitude of the resonance depend critcally on the…
Die Kristallstruktur des Chlorwasserstoffs
Zusammenfassung1.Es wird eine Apparatur zur Strukturermittlung kondensierter Gase nach der Debye-Scherrer-Methode beschrieben.2.Der in zwei Modifikationen kristallisierende Chlorwasserstoff wird…
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