Crystal Structure of Solid Hydrogen Chloride and Deuterium Chloride

@article{Sndor1967CrystalSO,
  title={Crystal Structure of Solid Hydrogen Chloride and Deuterium Chloride},
  author={E. S{\'a}ndor and Reginald C Farrow},
  journal={Nature},
  year={1967},
  volume={213},
  pages={171-172}
}
IT has long been known from measurements of specific heat1 that solid hydrogen chloride undergoes a first order phase transition at about 98.4° K. A similar phase transition was later found2 in solid deuterium chloride at about 105.0° K. X-ray powder photographs3 revealed that the crystal structure of hydrogen chloride was orthorhombic below the transition point and cubic above it. They also indicated that the chlorine atoms formed a face-centred lattice in both phases, but gave no clue… Expand
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References

SHOWING 1-5 OF 5 REFERENCES
Study of Phase Transitions by Means of Nuclear Magnetic Resonance Phenomena
Although the nuclear magnetic resonance condition generally depends only on the gyromagnetic ratio of the resonanting nuclei, the width and amplitude of the resonance depend critcally on the… Expand
Die Kristallstruktur des Chlorwasserstoffs
Zusammenfassung1.Es wird eine Apparatur zur Strukturermittlung kondensierter Gase nach der Debye-Scherrer-Methode beschrieben.2.Der in zwei Modifikationen kristallisierende Chlorwasserstoff wird… Expand
Ergebnisse der Tieftemperaturforschung
Abstract 1. Es wird ein Goldkalorimeter beschrieben, in dem die kalorischen Eigenschaften von DCl, DBr und DJ zwischen 15° abs und dem Siedepunkt untersucht werden. 2. Die Reindarstellung dieser Gase… Expand
Eine Doppelbande des festen Chlorwasserstoffs
ZusammenfassungIn derjenigen Spektralgegend, in der die Rotationsschwingungsbande des gasförmigen Chlorwasserstoffs liegt, wurde bei 870 abs. eine Doppelbande des festen Chlorwasserstoffs gefunden.… Expand
THE DIELECTRIC CONSTANT OF HYDROGEN CHLORIDE FROM 85 TO 165°K.