Cross-Coupling Reactions of Aryldiazonium Salts with Allylsilanes under Merged Gold/Visible-Light Photoredox Catalysis.

Abstract

A method for the cross-coupling reactions of aryldiazonium salts with trialkylallylsilanes via merged gold/photoredox catalysis is described. The reaction is proposed to proceed through a photoredox-promoted generation of an electrophilic arylgold(III) intermediate that undergoes transmetalation with allyltrimethylsilane to form allylarenes.

DOI: 10.1021/acs.orglett.7b01148

Cite this paper

@article{Akram2017CrossCouplingRO, title={Cross-Coupling Reactions of Aryldiazonium Salts with Allylsilanes under Merged Gold/Visible-Light Photoredox Catalysis.}, author={Manjur O Akram and Pramod S Mali and Nitin T Patil}, journal={Organic letters}, year={2017}, volume={19 12}, pages={3075-3078} }