Critical Behavior in Doping-Driven Metal-Insulator Transition on Single-Crystalline Organic Mott-FET.
@article{Sato2017CriticalBI,
title={Critical Behavior in Doping-Driven Metal-Insulator Transition on Single-Crystalline Organic Mott-FET.},
author={Yoshiaki Sato and Yoshitaka Kawasugi and Masayuki Suda and Hiroshi M. Yamamoto and Reizo Kato},
journal={Nano letters},
year={2017},
volume={17 2},
pages={
708-714
}
}We present the carrier transport properties in the vicinity of a doping-driven Mott transition observed at a field-effect transistor (FET) channel using a single crystal of the typical two-dimensional organic Mott insulator κ-(BEDT-TTF)2CuN(CN)2Cl (κ-Cl). The FET shows a continuous metal-insulator transition (MIT) as electrostatic doping proceeds. The phase transition appears to involve two-step crossovers, one in Hall measurement and the other in conductivity measurement. The crossover in…
13 Citations
Non-Fermi-liquid behavior and doping asymmetry in an organic Mott insulator interface
- PhysicsPhysical Review B
- 2019
High-$T_{\rm C}$ superconductors show anomalous transport properties in their normal states, such as the bad-metal and pseudogap behaviors. To discuss their origins, it is important to speculate…
Electric Double Layer Doping of Charge-Ordered Insulators α-(BEDT-TTF)2I3 and α-(BETS)2I3
- PhysicsCrystals
- 2021
Field-effect transistors based on strongly correlated insulators are an excellent platform for studying the electronic phase transition and simultaneously developing phase transition transistors.…
Two-dimensional ground-state mapping of a Mott-Hubbard system in a flexible field-effect device
- PhysicsScience Advances
- 2019
A two-dimensional ground-state mapping for a Mott insulator using an organic field-effect device is presented by simultaneously tuning the bandwidth and bandfilling to contribute toward elucidating one of the standard solutions for the Mott-Hubbard model.
Mechanism of superconductivity and electron-hole doping asymmetry in κ-type molecular conductors
- PhysicsNature Communications
- 2019
Unconventional superconductivity in molecular conductors is observed at the border of metal-insulator transitions in correlated electrons under the influence of geometrical frustration. The symmetry…
Two-dimensional hole gas in organic semiconductors
- Physics, Materials ScienceNature Materials
- 2021
The observed two-dimensional hole gas in solution-processed organic semiconductors in conjunction with an electric double layer using ionic liquids provides an opportunity to tailor low-dimensional electronic states using molecularly engineered heterointerfaces.
Organic phase-transition transistor with strongly correlated electrons
- Physics
- 2018
Phase transitions show large responses in physical properties including electrical conductivity changes caused by thermodynamic parameter control or by external stimuli. Thus, an element that shows…
Fabrication and Operation of Monolayer Mott FET at Room Temperature
- Chemistry
- 2017
Self-assembled monolayer FET based on a TTF derivative is described (FET = field-effect-transistor, TTF = tetrathiafulvalene). The molecule is anchored on an alumina dielectric layer through covalent…
Control of Organic Superconducting Field-Effect Transistor by Cooling Rate
- Chemistry, Physics
- 2019
A new superconducting field-effect transistor (FET) in the vicinity of bandwidth-controlled Mott transition was developed using molecular strongly correlated system κ-(BEDT-TTF)2Cu[N(CN)2]Br…
An Ambipolar Superconducting Field-Effect Transistor Operating above Liquid Helium Temperature.
- PhysicsAdvanced materials
- 2019
A novel "ambipolar" SC FET operating at normally OFF mode with TC of around 6 K is reported, which will contribute not only to fabricating SC circuits, but also to elucidating phase transitions of strongly correlated electron systems.
Field-, strain- and light-induced superconductivity in organic strongly correlated electron systems.
- PhysicsPhysical chemistry chemical physics : PCCP
- 2018
This perspective describes novel functionality of superconducting FETs, such as strain- and light-responsivity, and believes that the techniques and knowledge described here will contribute to advances in futuresuperconducting electronics as well as the understanding ofsuperconductivity in strongly correlated electron systems.
References
SHOWING 1-10 OF 67 REFERENCES
Mobility engineering and a metal-insulator transition in monolayer MoS₂.
- PhysicsNature materials
- 2013
Electrical transport measurements on MoS₂ FETs in different dielectric configurations are reported, showing clear evidence of the strong suppression of charged-impurity scattering in dual-gate devices with a top-gate dielectrics and a weaker than expected temperature dependence.
Mott physics and first-order transition between two metals in the normal state phase diagram of the two-dimensional Hubbard model
- Physics
- 2011
For doped two-dimensional Mott insulators in their normal state, the challenge is to understand the evolution from a conventional metal at high doping to a strongly correlated metal near the Mott…
Mott-Anderson Transition in Molecular Conductors: Influence of Randomness on Strongly Correlated Electrons in the κ-(BEDT-TTF)2X System
- Physics
- 2012
The Mott-Anderson transition has been known as a metal-insulator (MI) transition due to both strong electron-electron interaction and randomness of the electrons. For example, the MI transition in…
Metal-insulator transitions
- Physics
- 1998
Metal-insulator transitions are accompanied by huge resistivity changes, even over tens of orders of magnitude, and are widely observed in condensed-matter systems. This article presents the…
Superconductor–insulator transition in La2 − xSrxCuO4 at the pair quantum resistance
- PhysicsNature
- 2011
High-temperature superconductivity in copper oxides arises when a parent insulator compound is doped beyond some critical concentration; what exactly happens at this superconductor–insulator…
Doping a Mott insulator: Physics of high-temperature superconductivity
- Physics
- 2004
This article reviews the physics of high-temperature superconductors from the point of view of the doping of a Mott insulator. The basic electronic structure of cuprates is reviewed, emphasizing the…
Electron–hole doping asymmetry of Fermi surface reconstructed in a simple Mott insulator
- PhysicsNature communications
- 2016
This work investigates the doping asymmetry of an organic Mott insulator by carrying out electric-double-layer transistor measurements and using cluster perturbation theory, and predicts strongly anisotropic suppression of the spectral weight and a relatively uniform spectral weight results in the emergence of a non-interacting-like Fermi surface (FS) in the electron-doped state.
Field-induced carrier delocalization in the strain-induced mott insulating state of an organic superconductor.
- PhysicsPhysical review letters
- 2009
The gate-voltage dependence of the Hall coefficient shows that, unlike in conventional field-effect transistors, the effective mobility of dense hole carriers is enhanced by a positive gate voltage, which implies that carrier doping involves delocalization of intrinsic carriers that were initially localized due to electron correlation.
Unconventional critical behaviour in a quasi-two-dimensional organic conductor
- PhysicsNature
- 2005
It is found that the Mott transition in two dimensions is not consistent with known universality classes, as the observed collective behaviour has previously not been seen, but the universality class to which two-dimensional, repulsive electronic systems belongs remains unknown.
Bad-Metal Behavior Reveals Mott Quantum Criticality in Doped Hubbard Models.
- PhysicsPhysical review letters
- 2015
It is shown that for the doped Mott insulator regime, the coexistence dome and the associated first-order Mott metal-insulator transition are confined to extremely low temperatures, while clear signatures of Mott quantum criticality emerge across much of the phase diagram.


