Cp*-Substituted Boron Cations: The Effect of NHC, NHO, and CAAC Ligands.

Abstract

The effect of a ligand on the electron deficiency and Lewis acidity of the Cp*-substituted boron dication has been investigated experimentally and theoretically. In addition to the reported IMes- and N-heterocyclic olefin (NHO)-stabilized boron dications, the related cyclic alkylamino carbene (CAAC)-coordinated boron mono- and dications have also been… (More)

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