Coupling between Substituents as a Function of Cage Structure : Synthesis and Valence Ionized States of Bridgehead Disubstituted Parent and Hexafluorinated Bicyclo ACHTUNGTRENNUNG [ 1 . 1 . 1 ] pentane Derivatives C

Abstract

The indirect interaction of two molecular constituents Y’ and Y’’ mediated by an “inert” coupler Z (through-bond coupling, superexchange) has long been studied in the realm of electron and energy transfer, and has generated renewed interest in the context of molecular electronics, in which both highly conducting and strongly insulating moieties Z are needed… (More)

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