Coupled Thermodynamic and Kinetic Changes in the Electrochemistry of Ferrocenyl Monolayers Induced by Light.


We report on the light-induced systematic changes to the thermodynamics and kinetics of ferrocene units attached to a n-type silicon(100) photoelectrode. Both the reaction rate and the energetics of the charge transfer are simultaneously affected by changes in the intensity of the incident light. Cyclic voltammetry shows that increases in the intensity of… (More)
DOI: 10.1021/acs.langmuir.6b04106


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