Counter-ion perturbation of the fragmentation pathways of multiply charged anions: evidence for exit channel complexes on the fragmentation potential energy surfaces.


We report the first low-energy collisional excitation measurements and density functional theory calculations to characterize the ground state potential energy surfaces of contact ion-pair complexes that contain multiply charged anions (MCAs). Excitation of K+.Pt(CN)(4) (2-) and K+.Pt(CN)(6) (2-) result in fragmentation products associated with decay of the… (More)


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