Corresponding States Treatment of Nonelectrolyte Solutions

@article{Scott1956CorrespondingST,
  title={Corresponding States Treatment of Nonelectrolyte Solutions},
  author={R. Scott},
  journal={Journal of Chemical Physics},
  year={1956},
  volume={25},
  pages={193-205}
}
  • R. Scott
  • Published 1956
  • Chemistry
  • Journal of Chemical Physics
Recent theories of solutions (Prigogine and co‐workers; Salsburg and Kirkwood) use a theory of corresponding states to deduce the properties of solutions from theoretically derived properties of the pure components (e.g., from the Lennard‐Jones and Devonshire ``free volume'' or ``cell'' model). A characteristic of these theories is that they predict for molecules of the same size and dispersion force interactions a negative volume change on mixing.Since the ``cell'' model gives very poor… Expand
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