Correlation of the rates of solvolysis of benzoyl fluoride and a consideration of leaving-group effects.

@article{Kevill2004CorrelationOT,
  title={Correlation of the rates of solvolysis of benzoyl fluoride and a consideration of leaving-group effects.},
  author={Dennis Neil Kevill and Malcolm John D'Souza},
  journal={The Journal of organic chemistry},
  year={2004},
  volume={69 21},
  pages={7044-50}
}
The specific rates of solvolysis of benzoyl fluoride have been determined at 25.0 degrees C in 37 pure and binary solvents. Together with seven values from the literature, these give a satisfactory correlation over the full range of solvents when the extended Grunwald-Winstein equation is applied. The sensitivities to changes in solvent nucleophilicity and solvent ionizing power are very similar to those for octyl fluoroformate, suggesting that the addition step of an addition-elimination… CONTINUE READING

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