Copper complex of an iminodioxabicyclo[3.3.1]nonane pendant ligand: the first example of iminodioxocin bridgehead nitrogen coordination.

@article{Mandal2006CopperCO,
  title={Copper complex of an iminodioxabicyclo[3.3.1]nonane pendant ligand: the first example of iminodioxocin bridgehead nitrogen coordination.},
  author={Debashree Mandal and A-Qing Wu and Guo-Cong Guo and Debashis Ray},
  journal={Inorganic chemistry},
  year={2006},
  volume={45 22},
  pages={8826-8}
}
The pentadentate N4O amine-imine-naphthol ligand (HL(D)) containing rigid 8,16-imino-8H,16H-dinaphtho[2,1-b:2,1-f][1,5]dioxocin is formed preferentially, under visible light irradiation conditions, instead of the product H3L, expected from imidazolidine ring formation. A strained chelate bite enforces the first bridgehead nitrogen coordination to a copper… CONTINUE READING