Copper based metal-organic molecular ring with inserted Keggin-type polyoxometalate: a stable photofunctional host-guest molecular system.

@article{Fu2012CopperBM,
  title={Copper based metal-organic molecular ring with inserted Keggin-type polyoxometalate: a stable photofunctional host-guest molecular system.},
  author={Zhiyong Fu and Yu Zeng and Xiaoling Liu and Desheng Song and Shijun Liao and Jingcao Dai},
  journal={Chemical communications},
  year={2012},
  volume={48 49},
  pages={6154-6}
}
Keggin polyphosphotungstate cluster was captured by a porous molecular ring with light sensitizing TPT molecules as connectors and copper ions as nodes. The self-assembly reaction gives a stable host-guest supramolecular system, demonstrating efficient heterogeneous photocatalytic behavior for the degradation of methyl orange in near-neutral conditions. 

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