Copper(II) complexes of thioether containing an azoimidazolyl system. X-ray structure of Cu(SEtaaiNEt)Cl2 (SEtaaiNEt = 1-ethyl-2-{(o-thioethyl)phenylazo}imidazole)

@inproceedings{Banerjee2006CopperIICO,
  title={Copper(II) complexes of thioether containing an azoimidazolyl system. X-ray structure of Cu(SEtaaiNEt)Cl2 (SEtaaiNEt = 1-ethyl-2-\{(o-thioethyl)phenylazo\}imidazole)},
  author={Debasis Banerjee and Umasankar Ray and Sk. Jasimuddin and J. L. Liou and T Lu and Chittaranjan Sinha},
  year={2006}
}
Abstract The arylthioether diazonium ion is coupled with imidazole to synthesize tridentate imidazolylazothioether-based NN′S ligands. The reaction of CuCl 2  · 2H 2 O with NN′S ligands has synthesized penta-coordinated Cu(NN′S)Cl 2 compounds. The structure has been confirmed by an X-ray diffraction study in one case and also by other spectroscopic and magnetic properties. α-Diimine (N,N) ligands react with Cu(NN′S)Cl 2 to prepare ternary complexes, [Cu(NN′S)(N,N)] 2+ . Cu(NN′S)Cl 2 show a Cu… CONTINUE READING

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