Coordination polymers from a highly flexible alkyldiamine-derived ligand: structure, magnetism and gas adsorption studies.
@article{Hawes2015CoordinationPF,
title={Coordination polymers from a highly flexible alkyldiamine-derived ligand: structure, magnetism and gas adsorption studies.},
author={Chris S. Hawes and Nicholas F. Chilton and Boujemaa Moubaraki and Gregory P. Knowles and Alan L. Chaffee and Keith S. Murray and Stuart R. Batten and David R. Turner},
journal={Dalton transactions},
year={2015},
volume={44 40},
pages={
17494-507
}
}The synthesis and structural, magnetic and gas adsorption properties of a series of coordination polymer materials prepared from a new, highly flexible and internally functional tetrakis-carboxybenzyl ligand H4L derived from 1,2-diaminoethane have been examined. The compound poly-[Ni3(HL)2(OH2)4]·2DMF·2H2O 1, a two-dimensional coordination polymer, contains aqua- and carboxylato-bridged trinuclear Ni(II) clusters, the magnetic behaviour of which can be well described through experimental…
25 Citations
Coordination polymers from a flexible alkyldiamine-derived ligand
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The design, synthesis, structural characterisation and functional testing of a series of Cu(ii) coordination polymers containing flexible 4,4'-dithiodibenzoate ligand (4, 4'-DTBA), with or without auxiliary N-donor ligands are reported, which show reversible structural transformations triggered by either solvent exchange or thermal treatment.
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A new divergent homopiperazine-derived ligand N,N'-bis(4-carboxyphenyl)-1,4-diazacycloheptane H2L has been prepared, containing a semirigid saturated heterocyclic core which is capable of providing…
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Two new CuII coordination compounds, namely catena-poly and bis(3-amino-4-carboxybenzenesulfonate) dihydrate, have been obtained through the assembly between H2afsb and the CuII ion in the presence of the flexible N-donor ligands.
Metallomacrocycle-supported interpenetration networks assembled from binary N-containing ligands
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A new semi-rigid ligand of 4,4′-bis(1H-tetrazole)oxydibenzene (H2btzb) was designed and employed to assemble coordination compounds with the help of a secondary linker of 1,4-bis(1-imidazolyl)benzene…
Stable Fe(ii)-based coordination polymers: synthesis, structural diversity and catalytic applications in homo-coupling reactions.
- Chemistry, Materials ScienceDalton transactions
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The variable temperature magnetic susceptibilities of 1-3 prove that the metal centers of these polymers are bivalent and all of them exhibit a weak antiferromagnetic effect.
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