Coordination copolymerization mediated by Zn4O(CO2R)6 metal clusters: a balancing act between statistics and geometry.


Isolated successes of coordination copolymerization for the production of microporous coordination polymers (MCPs) have been reported recently; the logic for this synthetic approach has not been established nor have the key features of the synthetic conditions needed to generalize the method. Here, we establish guidelines for application of the… (More)
DOI: 10.1021/ja1065009


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