Coordination Chemistry of Aluminum, Gallium, and Indium at Transition Metals.

@article{Fischer1999CoordinationCO,
  title={Coordination Chemistry of Aluminum, Gallium, and Indium at Transition Metals.},
  author={Fischer and Weiss},
  journal={Angewandte Chemie},
  year={1999},
  volume={38 19},
  pages={
          2830-2850
        }
}
The current upswing in the interest in organoelement chemistry of Group 13 metals is attributed not least to the establishment of the coordination chemistry of R(a)E fragments (E=Al, Ga, In; a=1, 2) at d-block metals (M). Recently the availability of low-valent organoelement compounds as building blocks for synthesis has substantially enriched the structure chemistry of this class of compounds. The M-E bonding conditions and the question of the significance of M(d(pi))-E(p(pi)) backbonding as… CONTINUE READING
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