Convert Widespread Paraelectric Perovskite to Ferroelectrics.
@article{Wang2022ConvertWP, title={Convert Widespread Paraelectric Perovskite to Ferroelectrics.}, author={Hongwei Wang and Fujie Tang and Massimiliano Stengel and Hongjun Xiang and Qingzhi An and Tony Low and Xifan Wu}, journal={Physical review letters}, year={2022}, volume={128 19}, pages={ 197601 } }
While nature provides a plethora of perovskite materials, only a few exhibit large ferroelectricity and possibly multiferroicity. The majority of perovskite materials have the nonpolar CaTiO_{3}(CTO) structure, limiting the scope of their applications. Based on the effective Hamiltonian model as well as first-principles calculations, we propose a general thin-film design method to stabilize the functional BiFeO_{3}(BFO)-type structure, which is a common metastable structure in widespread CTO…
References
SHOWING 1-10 OF 37 REFERENCES
Why Are There So Few Perovskite Ferroelectrics
- Materials Science
- 2013
We use a combination of symmetry arguments and first-principles calculations to explore the connection between structural distortions and ferroelectricity in the perovskite family of materials. We…
Improper ferroelectricity in perovskite oxide artificial superlattices
- Materials ScienceNature
- 2008
It is shown that superlattices with very short periods possess a new form of interface coupling, based on rotational distortions, which gives rise to ‘improper’ ferroelectricity, and an approach is suggested,based on interface engineering, to produce artificial materials with unique properties.
Room-temperature polar ferromagnet ScFeO3 transformed from a high-pressure orthorhombic perovskite phase.
- Materials ScienceJournal of the American Chemical Society
- 2014
LiNbO3-type ScFeO3 is successfully obtained, a metastable phase converted from the orthorhombic perovskite formed under 15 GPa at elevated temperatures, providing a general and versatile strategy to create materials in which ferroelectricity and ferromagnetism coexist at high temperatures.
Epitaxial BiFeO3 Multiferroic Thin Film Heterostructures
- Physics, Materials ScienceScience
- 2003
Enhanced polarization and related properties in heteroepitaxially constrained thin films of the ferroelectromagnet, BiFeO3, and combined functional responses in thin film form present an opportunity to create and implement thin film devices that actively couple the magnetic and ferroelectric order parameters.
Polarization Enhancement in Perovskite Superlattices by Oxygen Octahedral Tilts
- Materials Science
- 2013
Interface Physics in Complex Oxide Heterostructures
- Materials Science
- 2011
Complex transition metal oxides span a wide range of crystalline structures and play host to an incredible variety of physical phenomena. High dielectric permittivities, piezo-, pyro-, and…
First-principles theory of structural phase transitions for perovskites: Competing instabilities
- Materials Science
- 1997
Abstract We extend our previous first-principles theory for perovskite ferroelectric phase transitions to treat also antiferrodistortive phase transitions. Our approach involves construction of a…
Atomically engineered ferroic layers yield a room-temperature magnetoelectric multiferroic
- Materials ScienceNature
- 2016
The results demonstrate a design methodology for creating higher-temperature magnetoelectric multiferroics by exploiting a combination of geometric frustration, lattice distortions and epitaxial engineering.
Probing the electronic structures of ternary perovskite and pyrochlore oxides containing Sn(4+) or Sb(5+).
- Materials ScienceInorganic chemistry
- 2004
The participation of the normally inert A- site cation in the electronic structure near the Fermi level can be considered an inductive effect, as it utilizes substitution on the A-site to directly modify the electronic structures of the SnO(3)(2)(-) framework.
Room temperature multiferroicity in orthorhombic LuFeO$_3$
- Physics
- 2014
From the measurement of dielectric, ferroelectric, and magnetic properties we observe simultaneous ferroelectric and magnetic transitions around $\sim$600 K in orthorhombic LuFeO$_3$. We also observe…