Controlling the variation of axial water exchange rates in macrocyclic lanthanide(III) complexes.

@article{Aime2002ControllingTV,
  title={Controlling the variation of axial water exchange rates in macrocyclic lanthanide(III) complexes.},
  author={Silvio Aime and Alessandro Barge and Andrei S Batsanov and Mauro Botta and Daniela Delli Castelli and Franco Fedeli and Armando Mortillaro and David Parker and Horst Puschmann},
  journal={Chemical communications},
  year={2002},
  volume={10},
  pages={1120-1}
}
The rate of axial water exchange in well-defined series of lanthanide complexes depends on the extent of second sphere hydration which is determined by complex hydrophobicity and the nature of the lanthanide ion and its counter-ion. 

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