Controlling Factors Determining the Selective HSCN Addition to Double Bonds and Their Application to the Synthesis of 7-Isothiocyano-7 , 8-- Dihydro-Bisabolene

@inproceedings{Oliveiraa2001ControllingFD,
  title={Controlling Factors Determining the Selective HSCN Addition to Double Bonds and Their Application to the Synthesis of 7-Isothiocyano-7 , 8-- Dihydro-Bisabolene},
  author={Cecilia M. de Oliveiraa and Cleuza C. da Silvac and Carol H. Collinsa and Anita J. Marsaiolia},
  year={2001}
}
  • Cecilia M. de Oliveiraa, Cleuza C. da Silvac, +1 author Anita J. Marsaiolia
  • Published 2001
A reatividade de duplas ligações terminal e trissubstituída de monoterpenos com HSCN foi examinada por CG evidenciando que fatores cinéticos são responsáveis pela adição quimiosseletiva em duplas ligações terminais em terpenos. O resultado mostra que a adição é cerca de 17 vezes mais rápida em duplas terminais do que em duplas trissubstituídas e que a presença do primeiro grupo SCN impede a entrada de um segundo grupo. A presença de um grupo hidroxila ou metoxila na molécula diminui… CONTINUE READING

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