Controlled dynamic helicity of a folded macrocycle based on a bisterephthalamide with a twofold Z-shaped structure.

Abstract

Dynamic helicity in a folded macrocycle and control of the helical preference are described. We designed macrocycle 1 with a dual mode of folding through the integration of two flexible units that are arranged twice to form a cyclic structure. As a folding unit, we used a terephthalamide skeleton and a Z-shaped hydrocarbon: the former acted as a control… (More)
DOI: 10.1002/asia.201402658

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