Controlled crystallization of CaCO3 under stearic acid monolayers

@article{Mann1988ControlledCO,
  title={Controlled crystallization of CaCO3 under stearic acid monolayers},
  author={Stephen Mann and Brigid R. Heywood and Sundara Rajam and James D. Birchall},
  journal={Nature},
  year={1988},
  volume={334},
  pages={692-695}
}
A fundamental concept in the study of biomineralization concerns the molecular recognition of inorganic materials at organized organic macromolecular substrates1. Here we investigate this concept through the use of stearic acid monolayers in the controlled crystallization of CaCO3 from supersaturated solutions. Whereas crystallization in the absence of a monolayer results in rhombohedral calcite crystals, the presence of an organized monolayer gives rise to oriented vaterite formation. The… CONTINUE READING
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