Control of optically active structure of thioether-phthalocyanine aggregates by chiral Pd(II)-BINAP complexes in toluene and at the toluene/water interface.

@article{Adachi2006ControlOO,
  title={Control of optically active structure of thioether-phthalocyanine aggregates by chiral Pd(II)-BINAP complexes in toluene and at the toluene/water interface.},
  author={Kenta Adachi and Kenji Chayama and Hitoshi Watarai},
  journal={Chirality},
  year={2006},
  volume={18 8},
  pages={599-608}
}
The Pd(II)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (BINAP)-mediated chiral assembly of thioether-derivatised phthalocyanatomagnesium(II) compounds (MgPc(SR)8, SR is benzylthio (SBz) or benzhydrylthio (Bh)) was formed in toluene and at the toluene/water interface, and investigated by means of UV-Vis absorption and circular dichroism (CD) spectroscopy combined with the centrifugal liquid-membrane (CLM) devise. Interfacial tension measurements indicated that, in the presence of PdSO4 in the… CONTINUE READING
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