Contingency and serendipity in the reactions of Fischer carbene complexes with conjugated triynes.

@article{Jiang2004ContingencyAS,
  title={Contingency and serendipity in the reactions of Fischer carbene complexes with conjugated triynes.},
  author={May Xiao-Wu Jiang and M. Rawat and W. Wulff},
  journal={Journal of the American Chemical Society},
  year={2004},
  volume={126 19},
  pages={
          5970-1
        }
}
  • May Xiao-Wu Jiang, M. Rawat, W. Wulff
  • Published 2004
  • Chemistry, Medicine
  • Journal of the American Chemical Society
  • The first examples of reactions of Fischer carbene complexes with triynes are reported. The regioselectivity of the reaction of the two different alkyne functions in the symmetrical triyne depends on the nature of the substituent of the triyne. Bis-silyl-substituted triynes react at the central alkyne unit, whereas bis-aryl- and bis-alkyl-substituted triynes react at the end alkyne unit. The reaction of a Fischer carbene complex with a phenyl substituent also reacts with a bis-silyl-substituted… CONTINUE READING
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