Construction of highly oriented crystalline surface coordination polymers composed of copper dithiooxamide complexes.

@article{Kanaizuka2008ConstructionOH,
  title={Construction of highly oriented crystalline surface coordination polymers composed of copper dithiooxamide complexes.},
  author={K. Kanaizuka and R. Haruki and O. Sakata and M. Yoshimoto and Y. Akita and H. Kitagawa},
  journal={Journal of the American Chemical Society},
  year={2008},
  volume={130 47},
  pages={
          15778-9
        }
}
Layer-by-layer bottom-up crystal engineering of metal-organic crystals at the surface of sapphire or glass from organic (rubeanic acid and derivatives) and inorganic (Cu(2+)) components which when mixed in solution form instantly an amorphous solid with high proton conduction. 
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References

Ultrathin organic films: From Langmuir-Blodgett to self assembly
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