Construction and application of a stoichiometric displacement model for retention in chiral recognition of molecular imprinting.

@article{Sun2004ConstructionAA,
  title={Construction and application of a stoichiometric displacement model for retention in chiral recognition of molecular imprinting.},
  author={Ruifeng Sun and Huimin Yu and Hui Luo and Zhongyao Shen},
  journal={Journal of chromatography. A},
  year={2004},
  volume={1055 1-2},
  pages={
          1-9
        }
}
To do an extensive investigation of the chiral recognition mechanism of the molecular imprinting technique, two kinds of enantio-selective molecularly imprinted polymers (MIPs), N-tert-butoxycarbonyl-L-tryptophan (N-Boc-L-Trp) and N-tert-butoxycarbonyl-L-tyramine (N-Boc-L-Tyr), were synthesized by photo-induced and thermal-induced polymerization, respectively, and were employed as the stationary phase in liquid chromatography. A stoichiometric displacement model for retention (SDM-R) was… CONTINUE READING