Consecutive carbon-carbon bond formation via the π-allylpalladium variant of the Heck reaction

@article{Nylund1994ConsecutiveCB,
  title={Consecutive carbon-carbon bond formation via the π-allylpalladium variant of the Heck reaction},
  author={Christine S. Nylund and John M. Klopp and Steven M Weinreb},
  journal={Tetrahedron Letters},
  year={1994},
  volume={35},
  pages={4287-4290}
}
Abstract Two CC bonds are readily formed by nucleophilic addition of stabilized carbanions to the π-allylpalladium intermediate regioselectively produced by the Heck reaction of a vinyl bromide and an unactivated olefin. An intramolecular version of this condensation gives functionalized carbobicyclic compounds as products. 

Similar Papers