Connecting the molecular scale to the continuum scale for diffusion processes in smectite-rich porous media.

Abstract

In this paper, we address the manner in which the continuum-scale diffusive properties of smectite-rich porous media arise from their molecular- and pore-scale features. Our starting point is a successful model of the continuum-scale apparent diffusion coefficient for water tracers and cations, which decomposes it as a sum of pore-scale terms describing… (More)
DOI: 10.1021/es903645a

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