Conjunctive functionalization of vinyl boronate complexes with electrophiles: a diastereoselective three-component coupling.

  title={Conjunctive functionalization of vinyl boronate complexes with electrophiles: a diastereoselective three-component coupling.},
  author={Roly J. Armstrong and Christopher Sandford and Cristina Garc{\'i}a-Ruiz and Varinder K. Aggarwal},
  journal={Chemical communications},
  volume={53 36},
A method for the conjunctive functionalization of vinyl boronate complexes with electrophiles is described. The overall process represents a three-component coupling between a vinyl boronic ester, carbon nucleophile and an electrophile, thus affording complex multifunctionalized products from simple starting materials. The diastereoselectivity (syn or anti) of this process is strongly dependent upon the nature of the electrophile. 
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