Conformational relaxation paths in tryptamine.

@article{Bhm2009ConformationalRP,
  title={Conformational relaxation paths in tryptamine.},
  author={Marcel B{\"o}hm and Robert Brause and Christoph Jacoby and Michael Schmitt},
  journal={The journal of physical chemistry. A},
  year={2009},
  volume={113 2},
  pages={488-55}
}
The relative fluorescence intensities of three conformers of tryptamine have been determined as a function of stagnation pressure and nozzle temperature in a supersonic expansion. The relative intensities of the conformers that are connected by different direct and indirect interconversion paths on the potential-energy hypersurface differ considerably depending on the experimental conditions. The energies of the local minima and some transition states interconnecting them are studied on the ab… CONTINUE READING
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