Conformational Dynamics of Triple Rotors: Tris(dimethylamino)methane, Triisopropylamine, and Related Molecules1

@inproceedings{Anderson1996ConformationalDO,
  title={Conformational Dynamics of Triple Rotors: Tris(dimethylamino)methane, Triisopropylamine, and Related Molecules1},
  author={James E. Anderson and Daniele Casarini and Lodovico Lunazzi},
  year={1996}
}
NMR spectra and their temperature-dependence are reported for tris(dimethylamino)methane (1), for tris(diethylamino)methane (2), for triisopropylamine (3), and for N,N-diisopropyl-3-pentylamine (4) and are discussed in terms of the conformations adopted and interconversion of these conformations, as indicated by molecular mechanics calculations. Solid state NMR spectra, obtained by freezing the neat liquids at low temperatures, were also used to support the conclusions of the conformational… CONTINUE READING

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