Conformational/configurational analysis of all the binding geometries of cobalt(III) bleomycin.

@article{Fedeles2001ConformationalconfigurationalAO,
  title={Conformational/configurational analysis of all the binding geometries of cobalt(III) bleomycin.},
  author={Flavia Fedeles and Marc Zimmer},
  journal={Inorganic chemistry},
  year={2001},
  volume={40 7},
  pages={1557-61}
}
No crystal structure of metallobleomycin (BLM) exists, and the exact coordination mode of the ligand is unknown. To date, spectroscopic investigations of BLM complexes and crystal structures of BLM models have been used to propose its metal coordination sites. This has led to contradictory interpretations of the metal coordination sphere in BLM. Inorganic… CONTINUE READING