Conformal Ionic Mixtures

  title={Conformal Ionic Mixtures},
  author={M. Blander and S. Yosim},
  journal={Journal of Chemical Physics},
  • M. Blander, S. Yosim
  • Published 1963
  • Chemistry
  • Journal of Chemical Physics
  • The excess free energy of mixing of molten reciprocal salt solutions (A+, B+, X—, Y—) has been calculated up to the second order by the perturbation method of Reiss, Katz, and Kleppa. The result is a power series containing integral powers of the ion fractions (concentrations). This demonstrates that mixtures of two salts of the same valence type cannot be considered as a mixture of a salt with a dielectric solvent.The first term in the series is proportional to the free‐energy change for the… CONTINUE READING
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    Contributions to molten salt chemistry by Ole J. Keppa
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