Confirmation of the molecular structure of tetramethylene diperoxide dicarbamide (TMDD) and its sensitiveness properties.


Conjecture existed as to the molecular structure of the crystalline organic peroxide reaction product derived from the acidified aqueous mixture of urea, formaldehyde, and hydrogen peroxide. This study used X-ray crystal structure determination to unequivocally define the reaction product as the 14-membered ring structure tetramethylene diperoxide… (More)
DOI: 10.1021/jp510827h

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