Configurational Isomerism in Polyoxovanadates.

@article{Mahnke2018ConfigurationalII,
  title={Configurational Isomerism in Polyoxovanadates.},
  author={L. K. Mahnke and Aleksandar Kondinski and Ulrike Warzok and C. N{\"a}ther and J. van Leusen and C. Schalley and K. Monakhov and P. K{\"o}gerler and W. Bensch},
  journal={Angewandte Chemie},
  year={2018},
  volume={57 11},
  pages={
          2972-2975
        }
}
A water-soluble derivative of the polyoxovanadate {V15 E6 O42 } (E=semimetal) archetype enables the study of cluster shell rearrangements driven by supramolecular interactions. A reaction unique to E=Sb, induced exclusively by ligand metathesis in peripheral [Ni(ethylenediamine)3 ]2+ counterions, results in the formation of the metastable α1 * configurational isomer of the {V14 Sb8 O42 } cluster type. Contrary to all other polyoxovanadate shell architectures, this isomer comprises an inward… Expand
14 Citations

Paper Mentions

Structural Chemistry of Metal‐Oxo Clusters
...
1
2
...

References

SHOWING 1-10 OF 31 REFERENCES
Semimetal-functionalised polyoxovanadates.
...
1
2
3
4
...