Condensation of nitriles with amides promoted by coordinatively unsaturated bis-nickel(II)-hydroxy complex: a new route to alkyl- and aryl-imidoylamidines.


A pentacoordinate bis(mu-hydroxy) nickel dimer promotes formation of alkyl- and aryl-imidoylamidines from nitriles and ureas or amides under mild conditions. 
DOI: 10.1039/b919634j

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