Compounds with the electron-rich [W6Cl18]2- cluster anion.


Cluster compounds of the general formula A(2)[W(6)Cl(18)] containing singly charged A cations (A = K, Rb, Ag, Tl, NH(4), N(C(2)H(5))(4), N(n-C(3)N(7))(4), N(n-C(4)H(9))(4)) and [W(6)Cl(18)](2-) anions have been synthesized. Compounds were obtained by W(6)Cl(18) reduction using methanol and the corresponding metal or (alkyl-)ammonium salts. The use of CoCp(2… (More)
DOI: 10.1021/ic8019843


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