Complete description of the interactions of a quadrupolar nucleus with a radiofrequency field. Implications for data fitting.


We present a theory, with experimental tests, that treats exactly the effect of radiofrequency (RF) fields on quadrupolar nuclei, yet retains the symbolic expressions as much as possible. This provides a mathematical model of these interactions that can be easily connected to state-of-the-art optimization methods, so that chemically-important parameters can… (More)
DOI: 10.1016/j.ssnmr.2013.03.002


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