Complete (1)H and (13)C NMR chemical shift assignments of mono-, di-, and trisaccharides as basis for NMR chemical shift predictions of polysaccharides using the computer program casper.

@article{Roslund2011CompleteA,
  title={Complete (1)H and (13)C NMR chemical shift assignments of mono-, di-, and trisaccharides as basis for NMR chemical shift predictions of polysaccharides using the computer program casper.},
  author={Mattias U Roslund and Elin S{\"a}w{\'e}n and J. Landstr{\"o}m and Jerk R{\"o}nnols and K Hanna M Jonsson and Magnus Lundborg and Mona V Svensson and Goeran Widmalm},
  journal={Carbohydrate research},
  year={2011},
  volume={346 11},
  pages={1311-9}
}
The computer program casper uses (1)H and (13)C NMR chemical shift data of mono- to trisaccharides for the prediction of chemical shifts of oligo- and polysaccharides. In order to improve the quality of these predictions the (1)H and (13)C, as well as (31)P when applicable, NMR chemical shifts of 30 mono-, di-, and trisaccharides were assigned. The reducing sugars gave two distinct sets of NMR resonances due to the α- and β-anomeric forms. In total 35 (1)H and (13)C NMR chemical shift data sets… CONTINUE READING