Competitive Excimer Formation and Energy Transfer in Zr-Based Heterolinker Metal-Organic Frameworks.


The spectroscopy and dynamics of a series of Zr-based MOFs in dichloromethane suspension are reported. These Zr-NADC MOFs were constructed by using different mixtures of 2,6-naphthalenedicarboxylate (NDC) and 4-amino-2,6-naphthalenedicarboxylate (NADC) as organic linkers. The fraction of NADC relative to NDC in these heterolinker MOFs ranges from 2 to 35… (More)
DOI: 10.1002/chem.201600669


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